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     IDENTITY: POLYPROPYLENE BUMPER -- AUTOLIGN

    MATERIAL SAFETY DATA SHEET

    PRODUCT CODE: Plastic bumper/Primer PAGE 1 of 18

    CONTROL DOCUMENT #: MS-00006 REV. DATE: 05/15/02

PART 1. POLYPROPYLENE BUMPER

    1.0 CHEMICAL PRODUCT AND COMPANY INFORMATION

    Product Name: Bumper Plastic Polypropylene

     Company Distributor: Keystone Automotive Industries

     700 East Bonita Avenue

     Pomona, CA 91767

     Company Phone: 1-800-772-5557

     Manufactured By: The Dow Chemical Company/Autolign

     24 hour Emergency Phone Number: 517-636-4400

     Customer Information Center: 1-800-258-2436

     Product Use: Replacement Crash Part

2.0 COMPOSITION/INFORMATION ON INGREDIENTS

    INGREDIENTS CAS NUMBER % BY WEIGHT

    Diethyl toluenediamine # 068479-98-1 29%

    Zinc stearate 000557-05-1 1-5%

    Polyalkylene ether polyol 009082-00-2 60-75%

    Polyoxypropylene diamine 009046-10-0 3-7%

3.0 HAZARDS IDENTIFICATION

    EMERGENCY OVERVIEW

    * Viscous liquid. Pungent odor. Causes eye irritation.

    * Note: Exposures in cured form not likely.

    POTENTIAL HEALTH EFFECTS (See Section 11 for toxicological data.)

    EYE: May cause slight eye irritation. May cause moderate corneal injury.

    SKIN: Prolonged exposure may cause moderate skin irritation. May cause allergic

    Document No. MS-00006

     IDENTITY: POLYPROPYLENE BUMPER -- AUTOLIGN

    MATERIAL SAFETY DATA SHEET

    PRODUCT CODE: Plastic bumper/Primer PAGE 2 of 18

    CONTROL DOCUMENT #: MS-00006 REV. DATE: 05/15/02

skin reaction in susceptible individuals. A single prolonged exposure is not likely to

    result in the material being absorbed through skin in harmful amounts.

    INGESTION: Single dose oral toxicity is considered to be low. Small amounts

    swallowed incidental to normal handling operations are not likely to cause injury;

    swallowing amounts larger than that may cause injury.

    INHALATION: At room temperature, vapors are minimal due to low vapor

    pressure. Certain operations may generate vapor or aerosol concentrations

    sufficient to cause irritation. Such operations include those in which the material is

    heated or sprayed as an aerosol (venting of vessels/lines).

CHRONIC EFFECTS

    SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: In rats, repeated dietary

    ingestion of diethyltoluenediamine (DETDA) has caused pancreatic, eye, liver and

    thyroid effects.

    CANCER INFORMATION: Diethyltoluenediamine (DETDA) has caused cancer in

    long-term animal studies. Increased numbers of tumors in the liver, thyroid &

    possibly the mammary glands were observed in rats given DETDA in their diet at

    exaggerated doses for 2 years.

    4.0 FIRST AID MEASURES

    EYES: Irrigate with flowing water immediately and continuously for 15 minutes.

    Consult medical personnel.

    SKIN: Wash off in flowing water or shower.

    INGESTION: If swallowed, seek medical attention. Do not induce vomiting unless

    directed to do so by medical personnel.

    INHALATION: Remove to fresh air if effects occur. Consult a physician.

    Document No. MS-00006

     IDENTITY: POLYPROPYLENE BUMPER -- AUTOLIGN

    MATERIAL SAFETY DATA SHEET

    PRODUCT CODE: Plastic bumper/Primer PAGE 3 of 18

    CONTROL DOCUMENT #: MS-00006 REV. DATE: 05/15/02

NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on

    judgment of the physician in response to reactions of the patient.

    5.0 FIRE FIGHTING MEASURES

    FLAMMABLE PROPERTIES

    FLASH POINT: 335 F, 168 C

    METHOD USED: PMCC, ASTM D93

FLAMMABILITY LIMITS

    LFL: Not determined

    UFL: Not determined

    HAZARDOUS COMBUSTION PRODUCTS: Combustion may produce carbon dioxide and carbon monoxide. Unidentified organic compounds may be formed

    during combustion which may present a greater hazard.

    OTHER FLAMMABILITY INFORMATION: Fire water run-off may be toxic. EXTINGUISHING MEDIA: Water fog, carbon dioxide, dry chemical, and foam.

    For large scale fires, alcohol resistant foams are preferred if available. General

    purpose synthetic foams or protein foams may function, but much less effectively.

    Water may be used to flush spills away from fire exposures and to dilute spills to

    non-flammable mixtures. If possible, contain fire water run-off. For large scale fires,

    direct water stream may cause violent frothing, but fine water spray may help

    control situation.

    FIRE FIGHTING INSTRUCTIONS: Keep unnecessary people away; isolate hazard area and deny unnecessary entry. When using water spray, boil-over may

    occur when the product temperature reaches the boiling point of water (tank-type

    scenarios, not spills).

    Document No. MS-00006

     IDENTITY: POLYPROPYLENE BUMPER -- AUTOLIGN

    MATERIAL SAFETY DATA SHEET

    PRODUCT CODE: Plastic bumper/Primer PAGE 4 of 18

    CONTROL DOCUMENT #: MS-00006 REV. DATE: 05/15/02

    PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: Wear positive-pressure self-

    contained breathing apparatus and full protective equipment.

6.0 ACCIDENTAL RELEASE MEASURES

    PROTECT PEOPLE: Isolate and confine spill area. Spills may be a slipping hazard.

    PROTECT THE ENVIRONMENT: Keep out of sewers, storm drains, surface

    waters and soil. Material is more dense than water and has limited water solubility

    surface. It will collect on the lowest surface.

    CLEANUP: Spills should be collected to prevent contamination of waterways

7.0 HANDLING AND STORAGE

    HANDLING: Exercise reasonable care and cleanliness. Spills of these organic

    liquids on hot fibrous insulations may lead to lowering of the autoignition

    temperature possibly resulting in spontaneous combustion. Advisable to agitate

    prior to use.

    The reaction of polyols and isocyanates generate heat. Contact of the reacting

    materials with skin or eyes can cause severe burns and may be difficult to remove

    from the affected areas. Immediately wash affected areas with plenty water and

    seek medical assistance.

    STORAGE: Store in sealed containers. Protect from atmospheric moisture. Replace

    outage with dry, inert atmosphere.

8.0 EXPOSURE CONTROLS/PERSONAL PROTECTION

    ENGINEERING CONTROLS: Provide general and/or local exhaust ventilation to

    control airborne levels below the exposure guide lines.

    Document No. MS-00006

     IDENTITY: POLYPROPYLENE BUMPER -- AUTOLIGN

    MATERIAL SAFETY DATA SHEET

    PRODUCT CODE: Plastic bumper/Primer PAGE 5 of 18

    CONTROL DOCUMENT #: MS-00006 REV. DATE: 05/15/02

    PERSONAL PROTECTIVE EQUIPMENT EYE/FACE PROTECTION: Use chemical goggles.

    SKIN PROTECTION: Use gloves impervious to this material when prolonged or

    frequently repeated contact could occur.

    RESPIRATORY PROTECTION: Atmospheric levels should be maintained below

    the exposure guideline. If respiratory irritation is experienced, use an approved air-

    purifying respirator.

    EXPOSURE GUIDELINE(S): Diethyltoluenediamine (DETDA): Dow IHG is 0.02

    ppm, Skin.

    Although some of the additives used in this product may have exposure guidelines,

    these additives are complexed with other components in the product and no

    exposure would be expected under normal handling conditions. A "skin" notation

    following the exposure guideline refers to the potential for dermal absorption of the

    material. It is intended to alert the reader that inhalation may not be the only route

    of exposure and that measures to minimize dermal exposures should be considered.

    9.0 PHYSICAL AND CHEMICAL PROPERTIES

    Appearance: Viscous liquid Odor: Pungent odor VAP Press: Nil

    VAP Density: >1

    Boiling Point: Not applicable Solubility in Water: Partially soluble Specific Gravity: 1.0311 25/25C

    10.0 STABILITY AND REACTIVITY

    Document No. MS-00006

     IDENTITY: POLYPROPYLENE BUMPER -- AUTOLIGN

    MATERIAL SAFETY DATA SHEET

    PRODUCT CODE: Plastic bumper/Primer PAGE 6 of 18

    CONTROL DOCUMENT #: MS-00006 REV. DATE: 05/15/02

CHEMICAL STABILITY: Stable under normal handling and storage conditions.

    CONDITIONS TO AVOID: None known

    INCOMPATIBILITY WITH OTHER MATERIALS: Strong acids and oxidizing materials. Also, alkali or alkaline earth metals such as copper, zinc or brass.

    HAZARDOUS DECOMPOSITION PRODUCTS: Combustion may produce carbon dioxide and toxic carbon monoxide. Unidentified organic compounds may be formed

    during combustion.

    HAZARDOUS POLYMERIZATION: Will not occur.

    11.0 TOXICOLOGICAL INFORMATION

    (See Section 3 for Potential Health Effects. For detailed toxicological data write or

    call the address or non-emergency number shown in Section 1)

    Acute

    INGESTION: The oral LD5O for rats is between 1000-2000 mg/kg.

    SKIN ABSORPTION: The LD5O for skin absorption in rabbits is >2000 mg/kg.

    MUTAGENICITY (EFFECTS ON GENETIC MATERIAL): For diethyltoluene-diamine, in vitro mutagenicity studies were negative in some cases and positive in

    other cases. Animal mutagenicity studies were negative.

    12.0 ECOLOGICAL INFORMATION

    (For detailed Ecological data, write or call the address or non-emergency number

    shown in Section 1)

    ENVIRONMENTAL FATE

    MOVEMENT & PARTITIONING: No bioconcentration is expected because of the

    high molecular weight (MW>1000). In the terrestrial environment, material is

    expected to remain in the soil. In the aquatic environment, material will sink and

    remain in the sediment.

    Document No. MS-00006

     IDENTITY: POLYPROPYLENE BUMPER -- AUTOLIGN

    MATERIAL SAFETY DATA SHEET

    PRODUCT CODE: Plastic bumper/Primer PAGE 7 of 18

    CONTROL DOCUMENT #: MS-00006 REV. DATE: 05/15/02

    DEGRADATION & PERSISTENCE: This water insoluble polymeric solid is expected to be inert in the environment. Surface photo degradation is expected

    with exposure to sunlight. No appreciable biodegradation is expected.

    ECOTOXICITY: Not expected to be acutely toxic, but pellets may mechanically

    cause adverse effects if ingested by waterfowl or aquatic life.

    13.0 DISPOSAL CONSIDERATIONS

    DISPOSAL: Any disposal practice must be in compliance with all federal,

    state/provincial, and local laws and regulations. State/provincial and local

    requirements for waste disposal may be more restrictive or otherwise different from

    federal laws and regulations. Regulations may also vary in different locations.

    Chemical additions, processing, storage, or otherwise altering this material may

    make the waste management information presented in this MSDS incomplete,

    inaccurate or otherwise inappropriate. Waste characterization and disposal

    compliance are the responsibility solely of the party generating the waste or

    deciding to discard or dispose of the material. None of these waste management

    options should be considered "arranging for disposal".

Product as sold is not a RCRA hazardous waste when disposed.

Do not allow into any sewers, on the ground, or into any body of water.

Refer to 40 CFR Section 261, and/or any other appropriate federal, state, provincial,

    or local requirements for proper classification information. For additional

    information see MSDS Regulatory Information (Section 15).

    THE KEYSTONE AUTOMOTIVE INDUSTRIES HAS NO CONTROL OVER THE

    MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES

    Document No. MS-00006

     IDENTITY: POLYPROPYLENE BUMPER -- AUTOLIGN

    MATERIAL SAFETY DATA SHEET

    PRODUCT CODE: Plastic bumper/Primer PAGE 8 of 18

    CONTROL DOCUMENT #: MS-00006 REV. DATE: 05/15/02

HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE

    PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS

    DESCRIBED IN MSDS SECTION 2 (Composition/Information On Ingredients)

FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include

    sending to a licensed, permitted: recycler, reclaimer, incinerator or other thermal

    destruction device, or landfill.

    14.0 TRANSPORT INFORMATION

    DOT CLASSIFICATION/DESCRIPTION: For DOT regulatory information, if required, transportation regulations, product shipping consult papers, or your Dow

    representative.

    CANADIAN TDG INFORMATION: For TDG regulatory information, if required, consult transportation regulations, product shipping papers, or your Dow

    representative.

    15.0 REGULATORY INFORMATION

    (Not meant to be all-inclusive--selected regulations represented)

    NOTICE: The information herein is presented in good faith and believed to be

    accurate as of the effective date shown above. However, no warranty, express or

    implied is given. Regulatory requirements are subject to change and may differ

    from one location to another; it is the buyer's responsibility to ensure that its

    activities comply with federal, state or provincial, and local laws. The following

    specific information is made for the purpose of complying with numerous federal,

    state or provincial, and local laws and regulations. See other sections for health and

    safety information.

    U.S. REGULATIONS

    Document No. MS-00006

     IDENTITY: POLYPROPYLENE BUMPER -- AUTOLIGN

    MATERIAL SAFETY DATA SHEET PRODUCT CODE: Plastic bumper/Primer PAGE 9 of 18

    CONTROL DOCUMENT #: MS-00006 REV. DATE: 05/15/02

SARA 313 INFORMATION: This product contains the following substances

    subject to the reporting requirements of Section 313 of Title III of the

    Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part

    372:

    CHEMICAL NAME CAS NUMBER CONCENTRATION

    ZINC COMPOUNDS 1 -5 %

SARA HAZARD CATEGORY: This product has been reviewed according to

    the EPA "Hazard Categories" promulgated under Sections 311 and 312 of the

    Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) is

    considered, under applicable definitions, to meet the following categories:

    An immediate health hazard

    A delayed health hazard

    TOXIC SUBSTANCES CONTROL ACT (TSCA): All ingredients are on the TSCA inventory or are not required to be listed on the TSCA inventory.

    STATE RIGHT-TO-KNOW: The following product components are cited on

    certain state lists as mentioned. Non-listed components may be shown in the

    composition section of the MSDS.

    PAl=Pennsylvania Hazardous Substance (present at greater than or equal to

    1.0%).

    PA3=Pennsylvania Environmental Hazardous Substance (present at greater

    than or equal to 1 .O%).

    OSHA HAZARD COMMUNICATION STANDARD: This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

    Standard, 29 CFR 1910.1200.

    COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION

    Document No. MS-00006

     IDENTITY: POLYPROPYLENE BUMPER -- AUTOLIGN

    MATERIAL SAFETY DATA SHEET

    PRODUCT CODE: Plastic bumper/Primer PAGE 10 of 18

    CONTROL DOCUMENT #: MS-00006 REV. DATE: 05/15/02

    AND LIABILITY ACT (CERCLA, or SUPERFUND): To the best of our

    knowledge, this product contains no chemical subject to reporting under

    CERCLA.

    CANADIAN REGULATIONS

    WHMIS INFORMATION: The Canadian Workplace Hazardous Materials

    Information System (WHMIS) Classification for this product is:

    D2B - eye or skin irritant. Refer elsewhere in the MSDS for specific warnings

    and safe handling information. Refer to the employer's workplace education

    program.

    CPR STATEMENT: This product has been classified in accordance with the

    hazard criteria of the Canadian Controlled Products Regulations (CPR) and

    the MSDS contains all the information required by the CPR.

    HAZARDOUS PRODUCTS ACT INFORMATION: This product contains the

    following ingredients which are Controlled Products and/or on the Ingredient

    Disclosure List (Canadian HPA section 13 and 14):

COMPONENTS: CAS# AMOUNT

    (%w/w) Polyalkylene ether polyol CAS # 9082-00-2 60-75% Polyoxypropylene diamine CAS# 9046-10-0 3-7% Zinc Stearate CAS# 557-05-1 1-5%

16.0 OTHER INFORMATION

    None

    Document No. MS-00006

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